IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand.
Fiche publication
Date publication
mars 2015
Auteurs
Membres identifiés du Cancéropôle Est :
Dr BELLEMIN-LAPONNAZ Stéphane
Tous les auteurs :
Cesar V, Mallardo V, Nano A, Dahm G, Lugan N, Lavigne G, Bellemin-Laponnaz S
Lien Pubmed
Résumé
The mesoionic 5-acetylimidazolium-4-olate serves as precursor for an anionic, hybrid NHC, "IMes-acac", consisting of fused diaminocarbene and acetylacetonato units, whose respective coordination abilities are evaluated by the formation of a series of representative copper(I) complexes illustrating the ambidentate character of the ligand.
Référence
Chem Commun (Camb). 2015 Mar 28;51(25):5271-4