Chirality-Driven Metallo-Copolymer Formation.
Fiche publication
Date publication
juillet 2012
Auteurs
Membres identifiés du Cancéropôle Est :
Dr BELLEMIN-LAPONNAZ Stéphane
Tous les auteurs :
Torres M, Heinrich B, Miqueu K, Bellemin-Laponnaz S
Lien Pubmed
Résumé
The combination of two heterochiral bisoxazoline ligands at one metal centre has been successfully used to generate coordination copolymers. The addition of a Zn metal ion to a monomer that has enantiopure C2-symmetric bisoxazoline units placed at either end does not favour the formation of self-aggregates. On the other hand, the use of a racemic mixture of the same ligand leads to the formation of a metallopolymeric assembly.
Référence
. 2012 Jul;21:3384-7.