Sieving and Clogging in PEG-PEGDA Hydrogel Membranes.
Fiche publication
Date publication
octobre 2023
Journal
Langmuir : the ACS journal of surfaces and colloids
Auteurs
Membres identifiés du Cancéropôle Est :
Dr SCHMUTZ Marc
Tous les auteurs :
Eddine MA, Carvalho A, Schmutz M, Salez T, de Chateauneuf-Randon S, Bresson B, Belbekhouche S, Monteux C
Lien Pubmed
Résumé
Hydrogels are promising systems for separation applications due to their structural characteristics (i.e., hydrophilicity and porosity). In our study, we investigate the permeation of suspensions of rigid latex particles of different sizes through free-standing hydrogel membranes prepared by photopolymerization of a mixture of poly(ethylene glycol) diacrylate (PEGDA) and large poly(ethylene glycol) (PEG) chains of 300,000 g·mol in the presence of a photoinitiator. Atomic force microscopy and cryoscanning electron microscopy (cryoSEM) were employed to characterize the structures of the hydrogel membranes. We find that the 20 nm particle permeation depends on both the PEGDA/PEG composition and the pressure applied during filtration. In contrast, we do not measure a significant permeation of the 100 nm and 1 μm particles, despite the presence of large cavities of 1 μm evidenced by the cryoSEM images. We suggest that the PEG chains induce local nanoscale defects in the cross-linking of PEGDA-rich walls separating the micrometer-sized cavities, which control the permeation of particles and water. Moreover, we discuss the decline of the permeation flux observed in the presence of latex particles compared to that of pure water. We suggest that a thin layer of particles forms on the surface of the hydrogels.
Référence
Langmuir. 2023 10 12;: