Second Generation of Near-Infrared Cyanine-Based Photocatalysts for Faster Organic Transformations.
Fiche publication
Date publication
septembre 2023
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
Auteurs
Membres identifiés du Cancéropôle Est :
Dr ELHABIRI Mourad
Tous les auteurs :
Sellet N, Clement-Comoy L, Elhabiri M, Cormier M, Goddard JP
Lien Pubmed
Résumé
A second generation of cyanine-based near-infrared photocatalysts has been developed to accelerate organic transformations. Cyanines were prepared and fully characterized prior to evaluation of their photocatalytic activities. Catalyst efficiency was determined using two model oxidation and reduction reactions. For the aza-Henry reaction, cyanines bearing an amino group on the heptamethine chain allowed to obtain the best results. For trifluoromethylation, the stability of the photocatalyst was found to be the key parameter for efficient and rapid conversion.
Mots clés
Cyanine, Near-infrared, Photosensitization, Redox potentials, photocatalysis
Référence
Chemistry. 2023 09 9;:e202302353