Insights into Solid-To-Solid Transformation of MOF Amorphous Phases.
Fiche publication
Date publication
août 2022
Journal
Inorganic chemistry
Auteurs
Membres identifiés du Cancéropôle Est :
Dr BELMONTE Thierry
Tous les auteurs :
Mezenov YA, Bruyere S, Krasilin A, Khrapova E, Bachinin SV, Alekseevskiy PV, Shipiloskikh S, Boulet P, Hupont S, Nomine A, Vigolo B, Novikov AS, Belmonte T, Milichko VA
Lien Pubmed
Résumé
Metal-organic frameworks (MOFs) have been recently explored as crystalline solids for conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and optical properties. The real-time control of such structural transformations and their outcomes still remain a challenge. Here, we use high-resolution transmission electron microscopy with 0.01 s time resolution to explore non-thermal (electron induced) amorphization of a MOF single crystal, followed by transformation into an amorphous nanomaterial. By comparing a series of -BTC (: Fe, Co, Co, Ni, and Cu; BTC: 1,3,5-benzentricarboxylic acid), we demonstrate that the topology of a metal cluster of the parent MOFs determines the rate of formation and the chemistry of the resulting phases containing an intact ligand and metal or metal oxide nanoparticles. Confocal Raman and photoluminescence spectroscopies further confirm the integrity of the BTC ligand and coordination bond breaking, while high-resolution imaging with chemical and structural analysis over time allows for tracking the dynamics of solid-to-solid transformations. The revealed relationship between the initial and resulting structures and the stability of the obtained phase and its photoluminescence over time contribute to the design of new amorphous MOF-based optical nanomaterials.
Référence
Inorg Chem. 2022 08 24;: