Chiral stimuli-responsive metallo-supramolecular assembly induced by Cu/Cu redox change.
Fiche publication
Date publication
juillet 2020
Journal
Chemical communications (Cambridge, England)
Auteurs
Membres identifiés du Cancéropôle Est :
Dr BELLEMIN-LAPONNAZ Stéphane
Tous les auteurs :
Marinova M, Bonnefont A, Achard T, Maisse-François A, Bellemin-Laponnaz S
Lien Pubmed
Résumé
We investigated the selective formation of homoleptic and heteroleptic metal complexes controlled by means of the chiral molecular instruction of the ligand and the coordination geometry of the metal. Our results showed that chiral self-recognition or self-discrimination may be induced by the CuI/CuII redox transition using cyclic voltammetry. The further use of chiral ditopic ligands led to metallo-supramolecular copolymers with stimuli-responsive controlled arrangement.
Référence
Chem. Commun. (Camb.). 2020 Jul 2;: