Optimal conditions for MS/MS sequencing of information-containing N-substituted polyurethanes.
Fiche publication
Date publication
avril 2020
Journal
Rapid communications in mass spectrometry : RCM
Auteurs
Membres identifiés du Cancéropôle Est :
Dr CARAPITO Christine
Tous les auteurs :
Charles L, Mondal T, Greff V, Razzini M, Monnier V, Burel A, Carapito C, Lutz JF
Lien Pubmed
Résumé
To prevent solubility issues faced with sequence-defined polyurethanes, a new family of digital polyurethanes was conceived with the alkyl coding chain held by the carbamate N atom and CH instead of OH as the ω termination. This led to different dissociation mechanisms that were explored prior to optimizing MS/MS sequencing.
Référence
Rapid Commun. Mass Spectrom.. 2020 Apr 20;:e8815