BODIPY atropisomer interconversion, face discrimination, and superstructure appending.
Fiche publication
Date publication
mars 2016
Journal
Chemical communications (Cambridge, England)
Auteurs
Membres identifiés du Cancéropôle Est :
Dr DECREAU Richard
Tous les auteurs :
Doulain PE, Goze C, Bodio E, Richard P, Decréau RA
Lien Pubmed
Résumé
A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two interconvertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.
Référence
Chem. Commun. (Camb.). 2016 Mar 25;52(24):4474-7