Synthesis of alternating metallocopolymers by chiral recognition.
Fiche publication
Date publication
août 2019
Journal
Chirality
Auteurs
Membres identifiés du Cancéropôle Est :
Dr BELLEMIN-LAPONNAZ Stéphane
Tous les auteurs :
Torres-Werlé M, Heinrich B, Maisse-François A, Bellemin-Laponnaz S
Lien Pubmed
Résumé
We report the synthesis of chiral enantiopure polytopic bridging ligands, which may lead to the formation of metallosupramolecular polymers with zinc (II) as metal linker. We show that chiral C -symmetric bisoxazoline ligands are useful moieties to efficiently generate heterochiral complexes and thus polymeric entities. The corresponding metallopolymers were further characterized by powder X-ray diffraction (PXRD) to obtain information on the level of crystallinity of our different metallopolymers.
Mots clés
chiral bisoxazoline, metallopolymer, polytopic ligand, zinc
Référence
Chirality. 2019 Aug 22;: