New tetrakis(4-aminophenyl)ethenes: synthesis and electrochemical investigations.

Fiche publication


Date publication

décembre 2005

Auteurs

Membres identifiés du Cancéropôle Est :
Pr SCHNEIDER Raphaël


Tous les auteurs :
Kuntz JF, Schneider R, Walcarius A, Fort Y

Résumé

Four novel functional conjugated tetraarylamines containing a tetraphenylenecore were synthesized via Ni-catalyzed aryl amination followed by McMurry olefination. Their electrochemical properties were studied by cyclic voltammetry, coulometry, and electrolysis monitored by UV-vis spectroscopy, and discussed with regard to those of the known tetrakis(dimethylaminophenyl)ethane. (c) 2005 Elsevier Ltd. All rights reserved.

Référence

Tetrahedron Lett. 2005 Dec 12;46(50):8793-7.