Novel carbocationic rearrangements of 1-styrylpropargyl alcohols.
Fiche publication
Date publication
janvier 2015
Auteurs
Membres identifiés du Cancéropôle Est :
Dr DESAUBRY Laurent
Tous les auteurs :
Basmadjian C, Zhang F, Desaubry L
Lien Pubmed
Résumé
The dehydration and subsequent cyclization reactions of 1-styrylpropargyl alcohols was examined. In the course of these studies, numerous scaffolds were synthesized, including a furan, a cyclopentenone, an acyclic enone and even a naphthalenone. The diversity of these structural motifs lies in novel cascades of reactions originating from a common carbocationic manifold.
Référence
Beilstein J Org Chem. 2015 Jun 15;11:1017-22